Title
Theoretical study of the saturated vapor pressure and enthalpy of sublimation ofsfullerite
Date Issued
01 January 1997
Access level
metadata only access
Resource Type
journal article
Author(s)
Abstract
The saturated vapor pressure and the enthalpy of sublimation of (Formula presented) has been calculated using a virial expansion for the gas and the correlative method of an unsymmetrized self-consistent field for the crystal, from the equilibrium point with the orientationally ordered phase up to the spinodal point estimated as (Formula presented) ≈1917 K. The Girifalco intermolecular potential is utilized. The dependence (Formula presented) (1/T) is close to a linear one, while Δ(Formula presented) decreases from 172.9 to 140.5 kJ/mole. The results are in good agreement with experimental data available between 600 and 990 K. Scaling of values obtained earlier for Ar gives an estimate for the triple point of the (Formula presented) fullerene: (Formula presented) ≈1460 K, (Formula presented) ≈740 Torr. © 1997 The American Physical Society.
Start page
6747
End page
6749
Volume
55
Issue
11
Language
English
OCDE Knowledge area
Física y Astronomía
Química física
Scopus EID
2-s2.0-0000446470
Source
Physical Review B - Condensed Matter and Materials Physics
ISSN of the container
10980121
Sources of information:
Directorio de Producción Científica
Scopus