Title
Defect Dynamics in Proton Irradiated CH3NH3PbI3 Perovskite Solar Cells
Date Issued
01 February 2017
Access level
open access
Resource Type
journal article
Author(s)
Brus V.V.
Lang F.
Bundesmann J.
Seidel S.
Denker A.
Landi G.
Neitzert H.C.
Rappich J.
Nickel N.H.
Institut für Silizium Photovoltaik
Publisher(s)
Blackwell Publishing Ltd
Abstract
Perovskite solar cells have been shown to be of extraordinary radiation hardness, considering high energetic (68 MeV) proton irradiation with doses up to 1013 p cm−2. In this study electrical and photoelectrical properties of perovskite solar cells with and without proton irradiation are analyzed in detail. The results reveal that proton irradiation improves the open circuit voltage, fill factor, and recombination lifetime of photogenerated charge carriers in perovskite solar cells. These enhancements are mainly a result of the lower nonradiative recombination losses in the proton irradiated devices. The proton treatment creates shallow traps, which may be associated with the proton induced point defects due to the displacements of atoms in the inorganic Pb–I framework, which act as unintentional doping sources and partially compensate deep traps originated from the photodegradation of methylammonium molecules.
Volume
3
Issue
2
Language
English
OCDE Knowledge area
Química física
Subjects
Scopus EID
2-s2.0-85010399682
PubMed ID
Source
Advanced Electronic Materials
Sponsor(s)
V.V.B. acknowledges the Alexander-von-Humboldt Foundation for financial support in the framework of the Georg Forster Research Fellowship.
Sources of information:
Directorio de Producción Científica
Scopus