Title
Long-range ferromagnetic order induced by a donor impurity band exchange in SnO<inf>2</inf>:Er<sup>3+</sup> nanoparticles
Date Issued
28 November 2013
Access level
metadata only access
Resource Type
journal article
Author(s)
University of Brasília
University of Brasília
Publisher(s)
AIP Publishing
Abstract
In this work, the structural and magnetic properties of Er-doped SnO 2 (SnO2:Er) nanoparticles are reported. The SnO 2:Er nanoparticles have been synthesized by a polymer precursor method with Er content from 1.0% to 10.0%. X-ray diffraction results indicate the formation of only the rutile-type structure in all samples. The estimated mean crystallite size shows a decrease from ∼10 to ∼4 nm when the Er content is increased from 1.0% to 10.0%. The particle size values have been corroborated by transmission electron microscopy technique. The thermal dependence of the magnetization is consistent with the 3+ oxidation state of erbium ions for all samples. A strong paramagnetic-like behavior coexisting with a ferromagnetic phase has been determined for samples with Er content below 5.0%. Above this concentration, only a paramagnetic behavior has been determined. Isothermal magnetization curves are consistent with the occurrence of long-range ferromagnetic order mediated by donor electrons forming bound magnetic polarons which overlap to produce a spin-split impurity band. © 2013 AIP Publishing LLC.
Volume
114
Issue
20
Language
English
OCDE Knowledge area
Física de partículas, Campos de la Física
Scopus EID
2-s2.0-84888593364
Source
Journal of Applied Physics
ISSN of the container
00218979
Sponsor(s)
This work was financially supported by the Brazilian agencies CNPq and FAP/DF. One of authors (F. H. Aragón) wants to thank the Brazilian agency CAPES for the scholarship. The authors are grateful to J. A. Dias for his help with the X-ray diffraction measurements.
Sources of information:
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