Title
Cd(II) biosorption using Lessonia kelps
Date Issued
15 May 2011
Access level
metadata only access
Resource Type
journal article
Abstract
Lessonia kelps (L. trabeculata and L. nigrescens) have been successfully used for the recovery of Cd(II) from near neutral solutions. The biomass was pre-treated with calcium chloride for stabilization of alginate-based compounds. SEM-EDAX analysis and FT-IR spectrometry analysis were used for identifying the modifications of the biomass. Sorption isotherms were performed at the optimum pH (i.e., pH 6) and the maximum sorption capacity reached up to 1 and 1.5mmolCdg-1 for L. nigrescens (L.n.) and L. trabeculata (L.t.), respectively. The Langmuir equation fits well experimental data. The temperature (in the range 20-40°C) had a more marked effect on affinity coefficient than on maximum sorption capacity. The influence of particle size, sorbent dosage, metal concentration and temperature was evaluated on uptake kinetics. The kinetic profiles that were modeled using the Crank equation (i.e., the resistance to intraparticle diffusion) were hardly affected by the temperature and the particle size contrary to the sorbent dosage and the metal concentration, which show greater impact. The pseudo-second order rate equation was also tested for the modeling of uptake kinetics. © 2011 Elsevier Inc.
Start page
487
End page
496
Volume
357
Issue
2
Language
English
OCDE Knowledge area
Química orgánica
Scopus EID
2-s2.0-79953028865
PubMed ID
Source
Journal of Colloid and Interface Science
ISSN of the container
00219797
Sponsor(s)
Authors thanks European Union for financial support under the ALFA program (Contract AML/190901/06/18414/II-0548-FC-FA), and the Program PREPA-PREFALC (for supporting the collaboration between Ecole des Mines d’Alès and the Universidad Peruana Cayetano Heredia). Authors also thank Jean-Marie Taulemesse for SEM–EDAX analyses.
Sources of information: Directorio de Producción Científica Scopus