Title
Size and pressure effects in the atom-phonon coupling model for spin crossover compounds
Date Issued
01 January 2008
Access level
metadata only access
Resource Type
journal article
Author(s)
Rotaru A.
Codjovi E.
Nasser J.
Stancu A.
Groupe d'Etude de la Matière Condensée (GEMaC)
Publisher(s)
American Institute of Physics Inc.
Abstract
The smallest size of a spin crossover particle which still exhibits hysteric behavior is an open question. It is clear that spin crossover is a cooperative phenomenon, which implies the dependence of the high spin fraction variation on the number of molecules within the system. We use the "atom-phonon coupling" model to explain the different results that have been recently published with regard to the critical dimension of a spin crossover system. In the second part of the paper, the applicability of the model to the pressure induced transition has been developed, and the results are in good agreement with what has been observed experimentally. © 2008 American Institute of Physics.
Volume
103
Issue
7
Language
English
OCDE Knowledge area
Física y Astronomía
Scopus EID
2-s2.0-42149128916
Source
Journal of Applied Physics
ISSN of the container
00218979
Sponsor(s)
This work was partially supported by the Agence Universitaire de la Francophonie (AUF, Reference No. 6313PS668), by the European Union FP6-Network of Excellence MAGMANet, and the PAI-BRANCUSI program financed by the French Ministry of Foreign Affair (EGIDE). A.R. is indebted to CNCSIS Romania for BD grant.
Sources of information: Directorio de Producción Científica Scopus