Title
Statistical effects in the absorption and optical activity of particulate suspensions.
Date Issued
01 January 1988
Access level
open access
Resource Type
journal article
Author(s)
University of New Mexico
Abstract
The phenomenon of Duysens flattening of the absorption spectra resulting from the inhomogeneous distribution of the chromophores in the solution is analyzed. These inhomogeneities are treated as localized statistical fluctuations in the concentration of the absorbing species, by using the Gaussian distribution. A law of absorbance is obtained, and the effect of light scattering on the flattening is also characterized. The flattening in the circular dichroism spectra of particulate suspensions is then analyzed. It is shown that the degree of flattening of the circular dichroism of a suspension is, in general, different from the corresponding flattening of its absorption spectrum. A quantitative relationship between the two effects is established.
Start page
8482
End page
8486
Volume
85
Issue
22
Language
English
OCDE Knowledge area
Física atómica, molecular y química Química física
Scopus EID
2-s2.0-0024110172
PubMed ID
Source
Proceedings of the National Academy of Sciences of the United States of America
ISSN of the container
00278424
Sponsor(s)
National Institute of General Medical Sciences, R37GM032543, NIGMS
Sources of information: Directorio de Producción Científica Scopus