Abstract: We analyze radiative processes of a quantum system composed by two identical two-level atoms interacting with a massless scalar field prepared in the vacuum state in the presence of perfect reflecting flat mirrors. We consider that the atoms are prepared in a stationary maximally entangled state. We investigate the spontaneous transitions rates from the entangled states to the collective ground state induced by vacuum fluctuations. In the empty-space case, the spontaneous decay rates can be enhanced or inhibited depending on the specific entangled state and changes with the distance between the atoms. Next, we consider the presence of perfect mirrors and impose Dirichlet boundary conditions on such surfaces. In the presence of a single mirror the transition rate for the symmetric state undergoes a slight reduction, whereas for the antisymmetric state our results indicate a slightly enhancement. Finally, we investigate the effect of multiple reflections by two perfect mirrors on the transition rates.