Title
State-of-the-art mid-frequency sputtered ZnO films for thin film silicon solar cells and modules
Date Issued
01 October 2003
Access level
metadata only access
Resource Type
conference paper
Author(s)
Müller J.
Schöpe G.
Kluth O.
Sittinger V.
Szyszka B.
Geyer R.
Lechner P.
Schade H.
Ruske M.
Dittmar G.
Bochem H.P.
Forschungszentrum Jülich GmbH
Abstract
This article reports on the use of ZnO films in silicon thin film p-i-n solar cells and modules. It summarizes the status in the final phase of a joint research project aiming at the development of high-quality ZnO/glass substrates feasible for an industrial solar module production. The samples were prepared by reactive mid-frequency (mf) sputtering on large area (60×100 cm 2) glass sheets using low-cost metallic Zn:Al targets. These ZnO films exhibit resistivities down to 2.6×10-4 Ω cm and high optical transmittance. Variation of the sputter pressure leads to films with significantly differing etching behavior in diluted acids. ZnO layers prepared in the high pressure regime develop strongly textured light scattering surfaces after etching, which is necessary to obtain highly efficient solar cells. Initial efficiencies of small area amorphous silicon (a-Si:H) cells on texture-etched ZnO-films prepared by mf-sputtering on 60×100 cm 2 soda-lime glass (3 mm thick) range from 8 to 9% (highest efficiency 9.2%, i-layer thickness 350 nm). First 0.6 m2 modules on ZnO prove the principal applicability of the films for an industrial manufacturing process. © 2003 Elsevier B.V. All rights reserved.
Start page
158
End page
162
Volume
442
Issue
February 1
Language
English
OCDE Knowledge area
Recubrimiento, Películas
Óptica
Subjects
Scopus EID
2-s2.0-0141636272
ISSN of the container
00406090
Conference
Thin Solid Films: Selected Papers from the 4th International COnference on Coating
Sponsor(s)
The authors thank all their colleagues and co-workers for measurements, technical assistance and numerous helpful discussions. This project is financed by the Bundesministerium für Wirtschaft und Technologie (BMWi) under contract no. 0329854A-F.
Sources of information:
Directorio de Producción Científica
Scopus