Title
Development of thin Pd-Ag supported membranes for fluidized bed membrane reactors including WGS related gases
Date Issued
02 March 2015
Access level
open access
Resource Type
journal article
Author(s)
Fernandez E.
Helmi A.
Coenen K.
Melendez J.
Viviente J.L.
Van Sint Annaland M.
Gallucci F.
TECNALIA
Publisher(s)
Elsevier Ltd
Abstract
This paper reports the preparation, characterization and stability tests of Pd-based thin membranes for fluidized bed membrane reactor applications. Various thin membranes have been prepared by simultaneous Pd-Ag electroless plating. A simple technique for sealing of the produced membranes is reported and discussed. The membranes have been characterized for single gas permeation, and afterwards used for permeation of mixtures of gases and under fluidization conditions. The membranes have shown very high permeation rates and perm-selectivity when used as permeators. When applied in fluidized bed reactors it has been found that the membranes are stable as long as no interaction between the fluidization catalyst and the membrane surface occurs. For some catalysts a strong chemical interaction between the catalyst and the membrane surface has been observed which caused a drastic decrease in the membrane flux.
Start page
3506
End page
3519
Volume
40
Issue
8
Language
English
OCDE Knowledge area
Química
Subjects
Scopus EID
2-s2.0-84922880066
Source
International Journal of Hydrogen Energy
ISSN of the container
03603199
Sponsor(s)
The presented work is funded within DEMCAMER project as part of the European Union 7th Framework Programme ( FP7/2007-2013 ) under grant agreement n° NMP3-LA-2011-262840 . Note: “The present publications reflect only the author's views and the Union is not liable for any use that may be made of the information contained therein.”
Sources of information:
Directorio de Producción Científica
Scopus