Title
Band-fluctuations model for the fundamental absorption of crystalline and amorphous semiconductors: A dimensionless joint density of states analysis
Date Issued
08 January 2019
Access level
metadata only access
Resource Type
journal article
Publisher(s)
Institute of Physics Publishing
Abstract
We develop a band-fluctuations model which describes the absorption coefficient in the fundamental absorption region for direct and indirect electronic transitions in disordered semiconductor materials. The model accurately describes both the Urbach tail and absorption edge regions observed in such materials near the mobility edge in a single equation with only three fitting parameters. An asymptotic analysis leads to the universally observed exponential tail below the bandgap energy and to the absorption edge model at zero Kelvin above it, for either direct or indirect electronic transitions. The latter feature allows the discrimination between the absorption edge and absorption tails, thus yielding more accurate bandgap values when fitting optical absorption data. We examine the general character of the model using a dimensionless joint density of states formalism with a quantitative analysis of a large amount of optical absorption data. Both heavily doped p-type GaAs and nano-crystalline Ga 1-x Mn x N, as examples for direct bandgap materials, as well as amorphous Si:H x , SiC:H x and SiN x , are modeled successfully with this approach. We contrast our model with previously reported empirical models, showing in our case a suitable absorption coefficient shape capable of describing various distinct materials while also maintaining the universality of the exponential absorption tail and absorption edge.
Volume
52
Issue
10
Language
English
OCDE Knowledge area
Física y Astronomía
Ingeniería eléctrica, Ingeniería electrónica
Subjects
Scopus EID
2-s2.0-85060236313
Source
Journal of Physics D: Applied Physics
ISSN of the container
00223727
Source funding
Sponsor(s)
This work was funded by the Research Management Office of the Pontificia Universidad Católica del Perú (DGI-PUCP) and the Peruvian National Fund for Scientific and Technological Development (FONDECYT), grant no. 147-2017. Additional support has been provided by the German Academic Exchange Service (DAAD) and FONDECYT, grant nos. 037-2016 and 132-2017. The authors are indebted to Martina Trahms (HZB) for the deposition of the SiNx samples, and to Fernando Da Silva and Douglas Leite (UNESP) for providing the Ga1−x MnxN absorption coefficient data.
Sources of information:
Directorio de Producción Científica
Scopus