Title
Effect of gamma-irradiation on the growth of ZnO nanorod films for photocatalytic disinfection of contaminated water
Date Issued
2011
Access level
restricted access
Resource Type
journal article
Author(s)
Abstract
The growth of ZnO nanorods on a flat substrate containing γ-irradiated seeds and their ability to photocatalytically eliminate bacteria in water were studied. The seed layer was obtained, by the spray pyrolysis technique, from zinc acetate solutions γ-irradiated within the range from 0 to 100. kGy. Subsequently, to grow the rods, the seeds were immersed in a basic solution of zinc nitrate maintained at 90 °C. The rate of crystal growth on the seed layer during the thermal bath treatment was kept constant.The resulting materials were characterized morphologically by scanning electron and atomic force microscopies; X-ray diffraction was used to study their morphology and structure and ultraviolet-visible spectroscopy to determine their absorbance. The obtained seed films were morphologically dependent on the radiation dose and this was correlated with the ZnO nanorod films which presented a texture in the (0. 0. 2) direction perpendicular to the substrate. The rods have a hexagonal mean cross section between 20 and 140. nm. Using these rods, the photocatalytic degradation of Escherichia coli bacteria in water was studied; a positive influence of the crystalline texture on the degradation rate was observed. © 2011 Elsevier Inc.
Start page
49
End page
55
Volume
364
Issue
1
Number
19
Language
English
Scopus EID
2-s2.0-80053189709
PubMed ID
Source
Journal of Colloid and Interface Science
ISSN of the container
0021-9797
Sponsor(s)
This work was supported by the Procyt-311-2009 Project and the 321-2009-Concytec-OAJ Project and MINCYT-CONCYTEC PE/09/01. We want acknowledge to “Laboratorio Nacional de Nanotecnologia” located at CIMAV and academic technician W. Antunez for help us to acquire SEM images. One of the authors, J. Rodriguez, wishes to thank the “Convenio de Desempeño, Universidad de Tarapacá-Mineduc” for financial support.
Sources of information:
Directorio de Producción Científica