Title
Influence of hydrodynamic conditions on the degradation of 1-butyl-3-methylimidazolium chloride solutions on boron-doped diamond anodes
Date Issued
01 June 2019
Access level
open access
Resource Type
journal article
Author(s)
de Oliveira Marcionilio S.M.L.
Crisafulli R.
Medeiros G.A.
de Sousa Tonhá M.
Garnier J.
Neto B.A.D.
Universidad de Brasilia
Publisher(s)
Elsevier
Abstract
This study assessed the influence of hydrodynamic conditions on the degradation process of 1-butyl-3-methylimidazolium chloride (BMImCl) solution on a boron-doped diamond anode in a filter-type electrochemical reactor configuration. The results show that this parameter did not significantly affect this process when operating in the laminar regime. However, in the transition regime (Re ≥ 2000), higher flow rates resulted in a faster removal of BMImCl and total organic carbon, making the process more efficient. Following BMImCl degradation, nitrates were generated at the cathode, then reduced at the cathode to ammonium; combination with free chloride produced at the anode led to the transformation of chloride into combined chlorine forms instead of more toxic oxianions such as chlorate and perchlorate. Thus, the flow rate can be a key parameter for defining operating conditions in which the target BMImCl is more effectively degraded with reduced generation of undesirable secondary products.
Start page
343
End page
350
Volume
224
Language
English
OCDE Knowledge area
Química física
Subjects
Scopus EID
2-s2.0-85062722715
PubMed ID
Source
Chemosphere
ISSN of the container
00456535
Sponsor(s)
The authors would like to thank Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) , Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) , DPP-UnB , Finatec , and Fundação de Apoio à Pesquisa do Distrito Federal (FAPDF, processes n. 0193–000.714/2016 and n. 0193–000.236/2014 ) for the financial support. We also would like to thank Prof. Ingrid Tavora Weber for the TOC analysis.
Sources of information:
Directorio de Producción Científica
Scopus