Title
Microcrystalline silicon for large area thin film solar cells
Date Issued
03 March 2003
Access level
metadata only access
Resource Type
conference paper
Author(s)
Roschek T.
Repmann T.
Müller J.
Schmitz R.
Appenzeller W.
Forschungszentrum Jülich GmbH
Abstract
We present a comprehensive study of microcrystalline silicon (μc-Si:H) solar cells prepared by plasma-enhanced chemical vapour deposition (PECVD) at 13.56 MHz excitation frequency. In the first step the cell development was performed in a small area PECVD reactor showing the relationship between the deposition process parameters and the resulting solar cell performance. Focus was on the influence of deposition pressure, electrode distance and the application of a pulsed plasma on high rate deposition of solar cells. Subsequent up-scaling to a substrate area of 30 × 30 cm2 confirmed the suitability of the process for large area reactors. The influence of i-layer deposition parameters on solar cell performance was studied directly in p-i-n cells prepared on textured ZnO. Solar cell efficiencies up to 9% were achieved at deposition rates of 5-6 Å/s for the i-layer using high plasma powers. Applied as bottom cell in a-Si:H/μc-Si:H tandem cells a stable cell efficiency of 11.2% could be obtained. The excellent homogeneity was proven by the realization of first modules with an aperture area of 689 cm2 and an active area initial efficiency of 10.3% (stable: 8.9%) using an established base technology for laser patterning and back contact sputtering at RWE Solar GmbH. © 2002 Elsevier Science B.V. All rights reserved.
Start page
157
End page
165
Volume
427
Issue
February 1
Language
English
OCDE Knowledge area
Recubrimiento, Películas
Scopus EID
2-s2.0-0037416712
Source
Thin Solid Films
ISSN of the container
00406090
Sponsor(s)
The authors thank their colleagues F. Birmans, J. Kirchhoff, O. Kluth, S. Michel, W. Reetz, G. Schöpe, B. Sehrbrock, H. Siekmann and H. Stiebig for extensive technical assistance, TCO preparation and helpful discussions. The solar module development was performed in close collaboration with W. Psyk, R. Geyer and P. Lechner from RWE Solar GmbH, Division Phototronics, Putzbrunn. We gratefully acknowledge financial support by the BMWi (contract Nos. 0329854A and 0329885) and the EU (contract No. ENK6-CT-2000-00321).
Sources of information: Directorio de Producción Científica Scopus