Title
Microcrystalline silicon deposition: Process stability and process control
Date Issued
16 July 2007
Access level
metadata only access
Resource Type
journal article
Author(s)
Forschungszentrum Jülich
Publisher(s)
Elsevier
Abstract
Applying in situ process diagnostics, we identified several process drifts occurring in the parallel plate plasma deposition of microcrystalline silicon (μc-Si:H). These process drifts are powder formation (visible from diminishing dc-bias and changing spatial emission profile on a time scale of 100 s), transient SiH4 depletion (visible from a decreasing SiH emission intensity on a time scale of 102 s), plasma heating (visible from an increasing substrate temperature on a time scale of 103 s) and a still puzzling long-term drift (visible from a decreasing SiH emission intensity on a time scale of 104 s). The effect of these drifts on the crystalline volume fraction in the deposited films is investigated by selected area electron diffraction and depth-profiled Raman spectroscopy. An example shows how the transient depletion and long-term drift can be prevented by suitable process control. Solar cells deposited using this process control show enhanced performance. Options for process control of plasma heating and powder formation are discussed. © 2006 Elsevier B.V. All rights reserved.
Start page
7455
End page
7459
Volume
515
Issue
19 SPEC. ISS.
Language
English
OCDE Knowledge area
Recubrimiento, Películas
Óptica
Subjects
Scopus EID
2-s2.0-34547576928
Source
Thin Solid Films
ISSN of the container
00406090
Sponsor(s)
The authors kindly thank W. Appenzeller, R. Carius, G. Dingemans, A. Gordijn, M. Hülsbeck, J. Klomfaβ, Y. Mai, and R. Schmitz for fruitful discussions and experimental support. Nuon is acknowledged for financial support. The research of W.M.M.K. was made possible through a fellowship of the Royal Netherlands Academy of Arts and Sciences (KNAW).
Sources of information:
Directorio de Producción Científica
Scopus