Title
Quantitative Contact Pressure Sensor Based on Spin Crossover Mechanism for Civil Security Applications
Date Issued
12 April 2018
Access level
metadata only access
Resource Type
journal article
Author(s)
Boukheddaden K.
Ritti M.H.
Bouchez G.
Sy M.
Dîrtu M.M.
Parlier M.
Garcia Y.
Publisher(s)
American Chemical Society
Abstract
Detailed studies of impacts on the new 1D spin transition polymer [Fe(hyetrz)3]I2·0.5EtOH have been performed under several controlled contact pressures, showing for high energy values a color change of the compound and allowing a visual detection of the spin transition from high-spin to low-spin states. By performing detailed investigations on freshly impacted samples, using spectroscopic diffuse optical reflectivity, we could follow the variation of the optical spectra as a function of the energy of the impact. The meticulous analysis of the obtained spectra allowed us to establish an absorption peak at 550 nm whose intensity and position well correlate to the energy of the impact. This concept provides a reliable method of measuring the energy of a chock even if the sample does not change its color so much in the visible range. This might be of high importance in several civil security applications, like transportation of artwork or other fragile valuable objects or even in the evaluation of the degree of alteration of a material after a collision.
Start page
7597
End page
7604
Volume
122
Issue
14
Language
English
OCDE Knowledge area
Ingeniería mecánica
Ingeniería eléctrica, Ingeniería electrónica
Scopus EID
2-s2.0-85045379339
Source
Journal of Physical Chemistry C
ISSN of the container
19327447
Sponsor(s)
This work was supported by CNRS (“Centre National de la Recherche Scientifique”), the University of Versailles and the Fonds National de la Recherche Scientifique (FNRS) (PDR T.01202.15), COST actions CM1305 and CA15128, the French “Minister̀ e de la Recherche” and the “Agence Nationale de la Recherche” (ANR Project BISTA-MAT: No.ANR-12-BS07-0030-01 and LIA IM-LED. M.M.D. acknowledges F.R.S.-FNRS for a Chargé de recherches position, and WBI for a postdoctoral stipendium. M.S. is indebted to Labex (Labo-ratoire d’Excellence) Charmmmat of University Paris Saclay for the postdoctoral fellowship.
Sources of information:
Directorio de Producción Científica
Scopus