Title
Magnetic frustration in low-dimensional substructures of hulsite ni5.15sn0.85(o2bo3)2
Date Issued
31 August 2018
Access level
metadata only access
Resource Type
journal article
Author(s)
Freitas D.C.
Passamani E.C.
Resende J.A.L.C.
Alzamora M.
Granado E.
Galdino C.W.
Baggio-Saitovitch E.
Continentino M.A.
Sanchez D.R.
Universidad Federal Fluminense
Publisher(s)
American Physical Society
Abstract
This paper presents an extensive study of the structural, magnetic, and thermodynamic properties of the hulsite Ni5.15Sn0.85(O2BO3)2. The crystal structure of the hulsite has two planar substructures formed by Ni and Sn atoms: one with rectangular configuration and the other with a triangular arrangement. These substructures are linked by the boron ions and by Ni in another site closer to the rectangular arrangement, resulting in a quasi-two-dimensional character. Thus, this system literally adds a new dimension to the study of oxyborates. Our results point to a complex magnetic behavior consistent with these substructures. The planes with rectangular arrangement form a complex magnetic ordering at 180 K (one of the highest magnetic transitions among the oxyborates). The other subsystem, formed by Ni atoms located in a two-dimensional triangular lattice, does not order down to temperatures as low as 3 K. The experimental results suggest a spin-liquid behavior for this subsystem. The magnetic moments of the ions between these planes also freeze at low temperatures. The two magnetic planes coexist as independent subsystems down to the lowest temperatures of our experiments.
Volume
98
Issue
5
Language
English
OCDE Knowledge area
Física nuclear Óptica
Scopus EID
2-s2.0-85053105999
Source
Physical Review B
ISSN of the container
24699950
Sponsor(s)
LNLS is acknowledged for concession of beam time. We also acknowledge LDRX-UFF (Universidade Federal Fluminense, Brazil) for use of their laboratory facilities. Support from the Brazilian agencies CNPq, FAPERJ, and FAPES is gratefully acknowledged.
Sources of information: Directorio de Producción Científica Scopus