Title
Efficient plasmonic coupling between Er3 +:(Ag/Au) in tellurite glasses
Date Issued
15 January 2012
Access level
open access
Resource Type
journal article
Author(s)
Ledemi Y.
Osorio S.P.A.
Manzani D.
Messaddeq Y.
Nunes L.A.O.
Marega E.
Universidad de Sao Paulo
Abstract
We report a systematic study of the localized surface plasmon resonance effects on the photoluminescence of Er3 +-doped tellurite glasses containing Silver or Gold nanoparticles. The Silver and Gold nanoparticles are obtained by means of reduction of Ag ions (Ag+ → Ag0) or Au ions (Au3 + → Au0) during the melting process followed by the formation of nanoparticles by heat treatment of the glasses. Absorption and photoluminescence spectra reveal particular features of the interaction between the metallic nanoparticles and Er3 + ions. The photoluminescence enhancement observed is due to dipole coupling of Silver nanoparticles with the 4I13/2 → 4I 15/2 Er3 + transition and Gold nanoparticles with the 2H11/2 → 4I13/2 (805 nm) and 4S3/2 → 4I13/2 (840 nm) Er 3 + transitions. Such process is achieved via an efficient coupling yielding an energy transfer from the nanoparticles to the Er3 + ions, which is confirmed from the theoretical spectra calculated through the decay rate. © 2011 Published by Elsevier B.V. All rights reserved.
Start page
399
End page
405
Volume
358
Issue
2
Language
English
OCDE Knowledge area
Termodinámica
Óptica
Subjects
Scopus EID
2-s2.0-81855201763
Source
Journal of Non-Crystalline Solids
ISSN of the container
00223093
Sources of information:
Directorio de Producción Científica
Scopus