Title
Fluidized bed membrane reactors for ultra pure H2 production - A step forward towards commercialization
Date Issued
01 March 2016
Access level
open access
Resource Type
journal article
Author(s)
TECNALIA
Publisher(s)
MDPI AG
Abstract
In this research the performance of a fluidized bed membrane reactor for high temperature water gas shift and its long term stability was investigated to provide a proof-of-concept of the new system at lab scale. A demonstration unit with a capacity of 1 Nm3/h of ultra-pure H2 was designed, built and operated over 900 h of continuous work. Firstly, the performance of the membranes were investigated at different inlet gas compositions and at different temperatures and H2 partial pressure differences. The membranes showed very high H2 fluxes (3.89 × 10-6 mol·m-2· Pa-1·s-1 at 400 °C and 1 atm pressure difference) with a H2/N2 ideal perm-selectivity (up to 21,000 when integrating five membranes in the module) beyond the DOE 2015 targets. Monitoring the performance of the membranes and the reactor confirmed a very stable performance of the unit for continuous high temperature water gas shift under bubbling fluidization conditions. Several experiments were carried out at different temperatures, pressures and various inlet compositions to determine the optimum operating window for the reactor. The obtained results showed high hydrogen recovery factors, and very low CO concentrations at the permeate side (in average <10 ppm), so that the produced hydrogen can be directly fed to a low temperature PEM fuel cell.
Volume
21
Issue
3
Language
English
OCDE Knowledge area
Ingeniería química
Química
Subjects
Scopus EID
2-s2.0-84963654039
PubMed ID
Source
Molecules
ISSN of the container
14203049
Sponsor(s)
Seventh Framework Programme 262840 FP7
Sources of information:
Directorio de Producción Científica
Scopus