Title
Theory of the interaction of light with large inhomogeneous molecular aggregates. I. Absorption
Date Issued
01 January 1986
Access level
metadata only access
Resource Type
journal article
Author(s)
University of New Mexico
Abstract
A general method to describe the spectroscopy of large, internally inhomogeneous particles is presented. The theory utilizes an approach similar to the one used by DeVoe in the treatment of the optical properties of polymers. The particle is divided into groups and the internal field is calculated by solving a self-consistent set of linear equations in the field amplitude at each group in the particle. It is found that if the particle is dense the intermediate and radiation coupling mechanisms must be included in addition to the dipole-dipole coupling. Through these coupling mechanisms it is found that the excitation generated at each group in the chromophore can delocalize over regions comparable to the size of the wavelength of light. The response of the particle to the light can then be described in terms of "collective modes" of excitation of the entire particle, the amplitude of each mode being controlled by the geometrical relation between the groups and the efficiency in energy transfer between any two groups in the aggregate. The spatially averaged equations of the absorbance for a collection of large inhomogeneous arbitrarily shaped aggregates are derived. © 1986 American Institute of Physics.
Start page
2961
End page
2971
Volume
84
Issue
6
Language
English
OCDE Knowledge area
Química Física atómica, molecular y química
Scopus EID
2-s2.0-0041798838
Source
The Journal of Chemical Physics
ISSN of the container
00219606
Sources of information: Directorio de Producción Científica Scopus