Title
Finite thermal diffusivity at onset of convection in autocatalytic systems: Continuous fluid density
Date Issued
01 January 1992
Access level
open access
Resource Type
journal article
Author(s)
West Virginia University
Abstract
The linear stability of exothermic autocatalytic reaction fronts is considered using the viscous thermohydrodynamic equations for a fluid with finite thermal diffusivity. For upward front propagation and a thin front, the vertical thermal gradient near the front is reminiscent of the Rayleigh-Bénard problem of a fluid layer heated from below. The problem is also similar to flame propagation, except that here the front propagation speed is limited by catalyst diffusion rather than by activation kinetics. For small density changes in a laterally unbounded system, the curvature dependence of the front propagation speed stabilizes perturbations with short wavelengths «<«c, whereas long wavelengths are unstable to convection. The critical wavelengths «c are calculated and compared with experiments and with theoretical results for a similar problem that is driven by a Rayleigh-Taylor instability arising from a discontinuous density difference at the reaction front. © 1992 The American Physical Society.
Start page
2320
End page
2327
Volume
45
Issue
4
Language
English
OCDE Knowledge area
Física atómica, molecular y química Física de partículas, Campos de la Física
Scopus EID
2-s2.0-0005881106
Source
Physical Review A
ISSN of the container
10502947
Sponsor(s)
Directorate for Education and Human Resources 8922106
Sources of information: Directorio de Producción Científica Scopus