Title
Dipolar recoupling in solid state NMR by phase alternating pulse sequences
Date Issued
01 April 2009
Access level
open access
Resource Type
journal article
Author(s)
Lin J.
Griffin R.
Khaneja N.
Massachusetts Institute of Technology
Publisher(s)
Academic Press Inc.
Abstract
We describe some new developments in the methodology of making heteronuclear and homonuclear recoupling experiments in solid state NMR insensitive to rf-inhomogeneity by phase alternating the irradiation on the spin system every rotor period. By incorporating delays of half rotor periods in the pulse sequences, these phase alternating experiments can be made γ encoded. The proposed methodology is conceptually different from the standard methods of making recoupling experiments robust by the use of ramps and adiabatic pulses in the recoupling periods. We show how the concept of phase alternation can be incorporated in the design of homonuclear recoupling experiments that are both insensitive to chemical shift dispersion and rf-inhomogeneity. © 2008 Elsevier Inc. All rights reserved.
Start page
145
End page
152
Volume
197
Issue
2
Language
English
OCDE Knowledge area
Radiología, Medicina nuclear, Imágenes médicas Bioquímica, Biología molecular
Scopus EID
2-s2.0-62149094734
PubMed ID
Source
Journal of Magnetic Resonance
ISSN of the container
10907807
Sponsor(s)
National Institute of Biomedical Imaging and Bioengineering -EB003151, P41EB002026 -NIBIB The research was supported in part by ONR 38A-1077404, AFOSR FA9550-05-1-0443 and NSF 0724057 and in part by the grants from the National Institutes of Biomedical Imaging and Bioengineering (EB003151 and EB002026).
Sources of information: Directorio de Producción Científica Scopus