Title
Continuous catalyst-free production of biodiesel through transesterification of soybean fried oil in supercritical methanol and ethanol
Date Issued
19 September 2013
Access level
metadata only access
Resource Type
journal article
Author(s)
Gonzalez S.L.
Sychoski M.M.
Callejas N.
Saibene M.
Vieitez I.
Jachmanián I.
Da Silva C.
Hense H.
Oliveira J.V.
Universidade Federal de Santa Catarina
Abstract
This work reports the production of fatty acid methyl esters (FAMEs) and fatty acid ethyl esters (FAEEs) by means of waste fried oil (WFO) transesterification using methanol and ethanol at supercritical conditions, in a continuous catalyst-free process. Transesterification experiments were performed from 573 to 623 K, at 10, 15, and 20 MPa, with oil/alcohol molar ratios of 1:20, 1:30, and 1:40 and water addition to alcohol of 0, 5, and 10 wt %. The extent of the reaction was explored using a novel parameter, convertibility, which corresponds to the maximum ester content attainable from the feedstock (92.1%). The highest FAME and FAEE contents achieved were 81.& and 82.2%, respectively. Results show that transesterification of WFO in methanol was more efficient than that in ethanol, the temperature had the strongest influence, and the addition of water considerably improved the ester yield. © 2013 American Chemical Society.
Start page
5253
End page
5259
Volume
27
Issue
9
Language
English
OCDE Knowledge area
Ingeniería del Petróleo, (combustibles, aceites), Energía, Combustibles
Tecnologías de bioprocesamiento, Biocatálisis, Fermentación
Subjects
Scopus EID
2-s2.0-84884517563
Source
Energy and Fuels
ISSN of the container
08870624
Sources of information:
Directorio de Producción Científica
Scopus