Field tests of organic solute transport behavior have often been monitored using small‐diameter wells (miniwells). To determine if experimental results could be significantly biased by sorption to, desorption from, or diffusion through sampling lines, dissolved concentrations of tetrachloroethene and carbon tetrachloride were measured in ground water samples collected simultaneously from the same spatial location during a forced‐gradient test in the Borden aquifer using polytetrafluoroethene (PTFE) and stainless steel miniwells (1/8‐inch O.D.). A semiautomated organic analytical system was used on‐site to obtain real‐time results, which avoided sample holding problems and permitted optimizing sampling times. The breakthrough curves (plots of concentration vs. time) for both organic compounds indicate that under the conditions of this experiment (low organic solute concentrations, short exposure time of sampling lines to the plume, adequate flushing of sampling lines) there is no significant difference between concentration histories (breakthrough curves) collected using a polytetrafluoroethene sampling line and those collected using a stainless steel sampling line. This suggests that organic solute tailing seen in this and also in a similar transport experiment previously conducted at the site is the result of transport processes in the aquifer rather than an artifact introduced by the PTFE miniwells. Copyright © 1992, Wiley Blackwell. All rights reserved