Title
Two-sublattice model for light-induced hysteresis in spin-crossover solids: Symmetry breaking and kinetic effects
Date Issued
13 November 2000
Access level
open access
Resource Type
research article
Author(s)
Parreira C.
Enachescu C.
Boukheddaden K.
Varret F.
Abstract
The recently developed macroscopic model of light-induced equilibrium of spin-crossover solids is extended to the case of two equivalent sublattices coupled `antiferromagnetically'. To do this, we use an Ising-like model involving two coupling parameters of opposite signs for the intra- and inter-sublattice interactions, previously introduced to describe the two-step static spin transition, and we have adapted the macroscopic master equation describing the time evolution of the system accordingly. We mostly report on the quasi-static solutions of the system, under constant light irradiation and for slow temperature variations. Light-induced thermal hysteresis loops are obtained and have typical two-step shapes for suitable sets of parameter values. The model predicts, in analogy with the static transition, a possible light-induced symmetry breaking between the structurally equivalent sublattices. Kinetic effects are briefly described.
Start page
9395
End page
9406
Volume
12
Issue
45
Language
English
OCDE Knowledge area
Física de la materia condensada
Scopus EID
2-s2.0-0034319672
Source
Journal of Physics Condensed Matter
Resource of which it is part
Journal of Physics Condensed Matter
ISSN of the container
09538984
Sources of information: Directorio de Producción Científica Scopus