Title
Luminescence and thermal lensing characterization of singly Eu3+ and Tm3+ doped Y2O3 transparent ceramics
Date Issued
01 January 2015
Access level
metadata only access
Resource Type
journal article
Author(s)
Kumar K.U.
Vermelho M.V.D.
Serivalsatit K.
Roberts S.A.
Kucera C.J.
Ballato J.
Jacobsohn L.G.
Jacinto C.
Universidade Federal de Alagoas, Maceió
Publisher(s)
Elsevier
Abstract
Transparent Y2O3 ceramics singly-doped with either Eu3+ or Tm3+ were fabricated by means of sequential consolidation steps at high pressure and temperature. These ceramics were characterized for their luminescence and thermal lensing behaviors, and the results compared to data on single crystals reported in literature. Thermal diffusivity, D, and conductivity, K, values of D=26×10-3 cm2/s and K=5.8 W/m K, respectively, for 1.0 mol% Eu3+ and 0.5 mol% Tm3+ singly-doped Y2O3 transparent ceramics were obtained. These values are about half of those for single crystal analogs. A small temperature coefficient of the optical path length change, ds/dT=3×10-6 K-1, was determined, making these materials suitable for applications requiring nearly athermal response. Selected spectroscopic properties were obtained by means of Judd-Ofelt analysis and together with thermal lens results provided absolute values for the fluorescence quantum efficiency of several levels, particularly 62% for the 5D0 level of Eu3+ and 84% for the 3F4 level of Tm3+.
Start page
306
End page
312
Volume
161
Language
English
OCDE Knowledge area
Ingeniería de materiales
Cerámica
Subjects
Scopus EID
2-s2.0-84922377993
Source
Journal of Luminescence
ISSN of the container
00222313
Sponsor(s)
This work was supported by Brazilian Agencies FAPEAL (Project PRONEX-NEXO no. 2009-09-006 ), FINEP (Financiadora de Estudos e Projetos) , CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico, grant INCT NANO(BIO)SIMES) , and CAPES (Coordenadoria de Aperfeiçoamento de Pessoal de Ensino Superior , Project PVE A077/2013 ). P.Y Poma is a graduate student supported by CAPES. Dr. KUK was supported by a Post Doctoral Fellowship grant of the Programa Nacional de Pós-Doutoramento(PNPD/CAPES) at the Universidade Federal de Alagoas (UFAL) through Project no. 02727/09-9 . Currently Dr. KUK is a post-doctorate of Project PVE A077/2013. This material is based upon work supported by the National Science Foundation under Grant no. 1207080 .
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