Title
Optical characterization and bandgap engineering of flat and wrinkle-textured FA(0.83)Cs(0.17)Pb(l(1-x)Brx)(3) perovskite thin films
Date Issued
2018
Access level
open access
Resource Type
journal article
Author(s)
Publisher(s)
American Institute of Physics Inc.
Abstract
The complex refractive indices of formamidinium cesium lead mixed-halide [FA0.83Cs0.17Pb(I1- xBrx)3] perovskite thin films of compositions ranging from x = 0 to 0.4, with both flat and wrinkle-textured surface topographies, are reported. The films are characterized using a combination of variable angle spectroscopic ellipsometry and spectral transmittance in the wavelength range of 190 nm to 850 nm. Optical constants, film thicknesses and roughness layers are obtained point-by-point by minimizing a global error function, without using optical dispersion models, and including topographical information supplied by a laser confocal microscope. To evaluate the bandgap engineering potential of the material, the optical bandgaps and Urbach energies are then accurately determined by applying a band fluctuation model for direct semiconductors, which considers both the Urbach tail and the fundamental band-to-band absorption region in a single equation. With this information, the composition yielding the optimum bandgap of 1.75 eV for a Si-perovskite tandem solar cell is determined. © 2018 Author(s).
Volume
123
Issue
17
Number
17
Language
English
Scopus EID
2-s2.0-85046633107
Source
Journal of Applied Physics
ISSN of the container
0021-8979
Sponsor(s)
This work was funded by the Research Management Office of the Pontificia Universidad Católica del Perú (PUCP), Project 2017-1-0030/502. Additional support was provided by the German Academic Exchange Service (DAAD) in conjunction with the Peruvian National Fund for Scientific and Technological Development (FONDECYT) (Grant Nos. 037-2016 and 132-2017), the Research Internationalization Office of the PUCP, the German Federal Ministry of Education and Research (BMBF), within the project “Materialforschung fur die Energiewende” (Grant No. 03SF0540), and the German Federal Ministry for Economic Affairs and Energy (BMWi) through the “PersiST” project (Grant No. 0324037C). A.T. gratefully acknowledges Cienciactiva CONCYTEC for an M.Sc. scholarship. S.B. gratefully acknowledges the Alexander von Humboldt Foundation for a Feodor Lynen Research Fellowship.
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