Title
Influence of excitation frequency, temperature, and hydrogen dilution on the stability of plasma enhanced chemical vapor deposited a-Si:H
Date Issued
01 October 1998
Access level
open access
Resource Type
journal article
Author(s)
Platz R.
Wagner S.
Hof C.
Shah A.
Wieder S.
Forschungszentrum Jülich
Publisher(s)
American Institute of Physics Inc.
Abstract
The first comparative study of dc, rf, and very high frequency (VHF) excitation for the plasma enhanced chemical vapor deposition of intrinsic layers of hydrogenated amorphous silicon (a-Si:H) is presented. The effects of hydrogen dilution on film stability are emphasized. Growth rates at comparable plasma power are presented for substrate temperatures between 100 and 300 °C and for various H2 dilution ratios. The optical band gap, H content, and electronic transport properties in the light-soaked state were measured. H2 dilution strongly reduces the growth rate for all techniques. The growth rate for the highest H2 dilution ratio is higher for VHF (∼4 Å/s) than for dc (∼3 Å/s) or rf (0.5-1 Å/s) excitation. In all three cases, increasing the substrate temperature reduces the optical gap and the H content CH. Raising the substrate temperature slightly enhances stability. H2 dilution increases the optical gap for all three techniques. The H content of rf- and VHF-deposited samples increases with increasing H2 dilution ratio, while in dc deposition it produces an initial drop of the H content, followed by an increase. In all three cases, H2 dilution improves the electronic transport properties of the material by roughly a factor of 2. The gain in stability is most pronounced for relatively small dilution; in the case of dc deposition, too strong a dilution even has an adverse effect on stability. We rule out a universal relation between hydrogen content of the a-Si:H films and their stability against light soaking. Enhanced stability may be obtained for films which incorporate either more or less hydrogen than standard a-Si:H. © 1998 American Institute of Physics.
Start page
3949
End page
3953
Volume
84
Issue
7
Language
English
OCDE Knowledge area
Ingeniería eléctrica, Ingeniería electrónica Recubrimiento, Películas
Scopus EID
2-s2.0-0001076246
Source
Journal of Applied Physics
ISSN of the container
00218979
Sources of information: Directorio de Producción Científica Scopus