Title
Hydrogen-bonded chain structure of a six-coordinate 5,10,15,20-tetraphenylporphinatomanganese(III) complex
Date Issued
16 April 2001
Access level
metadata only access
Resource Type
journal article
Author(s)
Osaka National Research Institute
Publisher(s)
Elsevier S.A.
Abstract
In methanolic solutions, disproportionation of the TCNQ anion radical to neutral TCNQ0 and the dianion TCNQ2- followed by aerobic oxidation of TCNQ2- results in the formation of methyl-4-dicyanomethylene benzoate anion (MDCB-). This anion coordinates to the manganese(III) atom of 5,10,15,20-tetraphenylporphinatomanganese(III) leading to the complex whose X-ray crystal structure is reported. The crystal had the monoclinic space group P21/n with unit cell dimensions a = 13.327(3), b = 20.236(6), c = 16.914(5) Å and β = 92.26(2)°. An important driving force behind the crystal packing is a hydrogen bonding interaction between non-identical ligands of adjacent molecules. © 2001 Elsevier Science B.V.
Start page
107
End page
111
Volume
315
Issue
1
Language
English
OCDE Knowledge area
Ingeniería química
Química inorgánica, Química nuclear
Subjects
Scopus EID
2-s2.0-0035897115
Source
Inorganica Chimica Acta
ISSN of the container
00201693
Sponsor(s)
The authors would like to thank the Agency of Industrial Science and Technology, Ministry of International Trade and Industry for the financial support under the research project ‘Harmonized Molecular Materials’. J.P.H. and J.S. acknowledge the Science and Technology Agency (STA) for providing STA fellowship.
Sources of information:
Directorio de Producción Científica
Scopus