Title
The Doping Mechanism of Halide Perovskite Unveiled by Alkaline Earth Metals
Date Issued
05 February 2020
Access level
open access
Resource Type
journal article
Author(s)
Phung N.
Félix R.
Meggiolaro D.
Al-Ashouri A.
Sousa E Silva G.
Hartmann C.
Hidalgo J.
Köbler H.
Mosconi E.
Lai B.
Gunder R.
Li M.
Wang K.L.
Wang Z.K.
Nie K.
Handick E.
Wilks R.G.
Marquez J.A.
Unold T.
Correa-Baena J.P.
Albrecht S.
De Angelis F.
Bär M.
Abate A.
Helmholtz-Zentrum Berlin für Materialien und Energie GmbH
Publisher(s)
American Chemical Society
Abstract
Halide perovskites are a strong candidate for the next generation of photovoltaics. Chemical doping of halide perovskites is an established strategy to prepare the highest efficiency and most stable perovskite-based solar cells. In this study, we unveil the doping mechanism of halide perovskites using a series of alkaline earth metals. We find that low doping levels enable the incorporation of the dopant within the perovskite lattice, whereas high doping concentrations induce surface segregation. The threshold from low to high doping regime correlates to the size of the doping element. We show that the low doping regime results in a more n-type material, while the high doping regime induces a less n-type doping character. Our work provides a comprehensive picture of the unique doping mechanism of halide perovskites, which differs from classical semiconductors. We proved the effectiveness of the low doping regime for the first time, demonstrating highly efficient methylammonium lead iodide based solar cells in both n-i-p and p-i-n architectures.
Start page
2364
End page
2374
Volume
142
Issue
5
Language
English
OCDE Knowledge area
Ingeniería de materiales
Scopus EID
2-s2.0-85079019284
PubMed ID
Source
Journal of the American Chemical Society
ISSN of the container
00027863
Sponsor(s)
We thank HZB for the allocation of synchrotron radiation beamtime. The research also used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under contract No. DE-AC02-06CH11357. N.P. thanks Prof. Susan Schorr, Dr. Joachim Breternitz for fruitful discussion on XRD analysis. N.P. thanks Carola Klimm for acquiring the SEM images. N.P. thanks the support of EE-NIMP group during manuscript preparation. H.K. thanks Sebastian, Dr. Aboma Merdasa and Hampus Näsström for the support during data analysis. D.M. and F.D.A. received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No 764047 of the ESPRESSO project. The Ministero Istruzione dell’Università e della Ricerca (MIUR) and the University of Perugia are acknowledged for the financial support through the program “Dipartimenti di Eccellenza 2018-2022” (grant AMIS) to F.D.A. A.A.A. and S.A. acknowledge the German Federal Ministry of Education and Research (BMBF) for funding of the Young Investigator Group (Grant No. 03SF0540) within the project “Materialforschung für die Energiewende.” M. L. acknowledges funding from the Collaborative Innovation Center of Suzhou Nano Science and Technology and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD). Horizon 2020 Framework Programme - 764047 - H2020 Università degli Studi di Perugia
Sources of information: Directorio de Producción Científica Scopus