Title
TCO and light trapping in silicon thin film solar cells
Date Issued
01 December 2004
Access level
metadata only access
Resource Type
journal article
Author(s)
Müller J.
Springer J.
Vanecek M.
Forschungszentrum Jülich GmbH
Abstract
For thin film silicon solar cells and modules incorporating amorphous (a-Si:H) or microcrystalline (μc-Si:H) silicon as absorber materials, light trapping, i.e. increasing the path length of incoming light, plays a decisive role for device performance. This paper discusses ways to realize efficient light trapping schemes by using textured transparent conductive oxides (TCOs) as light scattering, highly conductive and transparent front contact in silicon p-i-n (superstrate) solar cells. Focus is on the concept of applying aluminum-doped zinc oxide (ZnO:Al) films, which are prepared by magnetron sputtering and subsequently textured by a wet-chemical etching step. The influence of electrical, optical and light scattering properties of the ZnO:Al front contact and the role of the back reflector are studied in experimentally prepared a-Si:H and μc-Si:H solar cells. Furthermore, a model is presented which allows to analyze optical losses in the individual layers of a solar cell structure. The model is applied to develop a roadmap for achieving a stable cell efficiency up to 15% in an amorphous/macrocrystalline tandem cell. To realize this, necessary prerequisites are the incorporation of an efficient intermediate reflector between a-Si:H top and μc-Si:H bottom cell, the use of a front TCO with very low absorbance and ideal light scattering properties and a low-loss highly reflective back contact. Finally, the mid-frequency reactive sputtering technique is presented as a promising and potentially cost-effective way to up-scale the ZnO front contact preparation to industrial size substrate areas. © 2004 Elsevier Ltd. All rights reserved.
Start page
917
End page
930
Volume
77
Issue
6
Language
English
OCDE Knowledge area
Óptica Recubrimiento, Películas
Scopus EID
2-s2.0-9944234069
Source
Solar Energy
ISSN of the container
0038092X
Sponsor(s)
The authors thank Manfred Ruske of Applied Films GmbH & Co. KG (Alzenau, Germany) and Peter Lechner and Horst Schade of RWE SCHOTT Solar GmbH (Putzbrunn, Germany) for their support and helpful discussions, H.P. Bochem for SEM measurements and O. Kluth for valuable information and many discussions on the material and structural properties of ZnO films. Technical assistance from G. Schöpe, W. Appenzeller, J. Kirchhoff and H. Siekmann is gratefully acknowledged. This work was supported by the German Ministry of Economic Affairs (BMWi, contract no. 0329854A and 0329923A) and by the European Commission (contract no. ENK6-CT-2000-00321).
Sources of information: Directorio de Producción Científica Scopus