Title
Mononuclear copper(II) complexes of dioxaalkylene and alkylene bridged bis-isoureas
Other title
Mononukleare Kupfer(II)-Komplexe von dioxaalkylen-und alkylenverbrückten Bis-isoharnstoffen
Date Issued
01 January 2001
Access level
metadata only access
Resource Type
journal article
Author(s)
Publisher(s)
Wiley-VCH Verlag
Abstract
By reaction of N-benzoylthiocarbamic-O,S-diethyl-ester with primary diamines (oxa)alkylene bridged isoureas 1 have been prepared. They yield with CuII neutral chelates 2 with tetradentate ligand coordination. The structures of the ligand la and of the related CuII complex 2a have been determined by X-ray crystal structure analysis. They show an enamine tautomer in the ligand and a slightly tetrahedrally distorted coordination with an (oxa)alkylene bridge between the trans arranged N ligator atoms in the complex. © WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001.
Start page
1877
End page
1881
Volume
627
Issue
8
Language
German
OCDE Knowledge area
Mineralogía
Subjects
Scopus EID
2-s2.0-0035628334
Source
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN of the container
00442313
Sources of information:
Directorio de Producción Científica
Scopus