Title
Nematic Order Imposes Molecular Weight Effect on Charge Transport in Conjugated Polymers
Date Issued
28 March 2018
Access level
open access
Resource Type
journal article
Author(s)
Zhang W.
Milner S.
University Park
Publisher(s)
American Chemical Society
Abstract
Nematic order, in the bulk or at interfaces, is ubiquitous for semiflexible conjugated polymers. Nevertheless, the effect of liquid crystalline order on charge transport remains unclear. Using an analytical model, we demonstrate that nematic order leads to an enhancement in charge mobilities when compared to isotropic chains. Furthermore, we predict a quadratic dependence of the charge mobility on molecular weight of the chains. Analysis of the probability of forming hairpin defects also shows how the persistence length affects charge transport in conjugated polymers. We speculate that the prevalence of nematic order in conjugated polymers explains the reported increase in charge mobilities with molecular weight.
Start page
413
End page
421
Volume
4
Issue
3
Language
English
OCDE Knowledge area
Ingeniería química
Scopus EID
2-s2.0-85044752686
Source
ACS Central Science
ISSN of the container
23747943
Sponsor(s)
Funding support from the National Science Foundation under award number DMR-1629006 is gratefully acknowledged.
Sources of information: Directorio de Producción Científica Scopus