The 3-n-propyl-1-azonia-4-azabicyclo[2.2.2]octanechloride/silica hybrid polymer was synthesized, using the sol-gel method, by varying the organic content. The samples were characterized using infrared spectroscopy (FTIR), scanning electron microscopy (SEM), N2 adsorption-desorption isotherms and thermogravimetric analysis. The polymer morphology could be controlled by the choice and amount of the organic precursor added. The dispersion of the organic/inorganic phases was shown to be in molecular or nanometric level. The organic content elevation produced a decrease in the surface area and pore volume due to the organic pore blocking effect. © 2003 Published by Elsevier Ltd.