The study evaluates five types of commercial textiles with different cotton and polyester contents widely used in the garment industry. These textile samples have been subjected to treatment by the exhaustion method using zinc oxide nanoparticles (NP ZnO) (textile functionalization) with the aim of improving their efficiency in blocking UV radiation. The ZnO nanoparticles have been obtained by two methods: The green or also called biosynthesis (using the extract of Coriandrum sativum as an organic reducing agent), and the chemical method (using NaOH as an inorganic reducing agent). The results related to the green method show having achieved a defined geometric configuration with an average size of 97.77 nm (SD: 9.53). On the contrary, the nanostructures obtained by the chemical method show pentagonal configurations with average sizes of 113 nm (SD: 6.72). The textiles functionalized with NP ZnO obtained by biosynthesis showed a better efficiency in blocking ultraviolet radiation (UV).