Title
Niobium oxide dispersed on a carbon-ceramic matrix, SiO2/C/ Nb2O5, used as an electrochemical ascorbic acid sensor
Date Issued
15 November 2010
Access level
metadata only access
Resource Type
journal article
Author(s)
Villis P.
Arguello J.
Landers R.
Benvenutti E.
Gushikem Y.
Instituto de Química
Publisher(s)
Elsevier B.V.
Abstract
A film of niobium oxide was immobilized on a SiO2/C carbon-ceramic matrix (specific surface area 270 m2 g-1) and characterized by N2 adsorption-desorption isotherms, scanning electron microscopy, X-ray photoelectron spectroscopy and atomic force microscopy. This new carbon-ceramic material, SiO2/C/Nb 2O5, was used for construction of electrodes, and it shows ability to improve the electron-transfer between the electrode surface and ascorbic acid. The electrocatalytic oxidation of ascorbic acid was made by differential pulse and cyclic voltammetry techniques, making it potentially useful for developing a new ascorbic acid sensor. © 2010 Elsevier B.V.
Start page
241
End page
248
Volume
83
Issue
1
Language
English
OCDE Knowledge area
Electroquímica
Scopus EID
2-s2.0-78049355385
Source
Talanta
ISSN of the container
00399140
Sponsor(s)
The authors thank FAPESP for fellowships L.T.A., process 06/61214-4 and financial support. They also thank the Brazilian Synchrotron Light Laboratory (LNLS) for the AFM/EFM measurements and are grateful to Prof. Carol H. Collins for manuscript review.
Sources of information: Directorio de Producción Científica Scopus