Title
High-resolution stimulated Raman spectroscopy and analysis of the ν2 and ν3 bands of C2<H4
Date Issued
01 July 2013
Access level
metadata only access
Resource Type
journal article
Author(s)
Ballandras A.
Cirtog M.
Bourgeois M.T.
Rotger M.
Bermejo D.
Martínez R.Z.
Doménech J.L.
Boudon V.
Universidad de Oriente
Publisher(s)
John Wiley and Sons Ltd
Abstract
The high-resolution stimulated Raman spectra of the ν2 and ν3 bands of C2H4 have been recorded and analyzed separately by means of the tensorial formalism developed in Dijon and Reims for X2Y4 asymmetric-top molecules. For the ν2 band, a total of 191 lines were assigned and fitted. We obtained a global root mean square deviation of 1.86 × 10-3 cm-1. For the ν3 band analyzed in interaction with the ν6 infrared band, a total of 185 lines were assigned and fitted. We obtained a global root mean square deviation of 1.29 × 10-3 cm- 1. Both analyses lead to very satisfactory synthetic spectra. Copyright © 2013 John Wiley & Sons, Ltd.
Start page
1033
End page
1038
Volume
44
Issue
7
Language
English
OCDE Knowledge area
Física de la materia condensada Química orgánica
Scopus EID
2-s2.0-84880047348
Source
Journal of Raman Spectroscopy
ISSN of the container
03770486
Sources of information: Directorio de Producción Científica Scopus