Title
Broadband homonuclear correlation spectroscopy at high magnetic fields and MAS frequencies
Date Issued
15 February 2006
Access level
metadata only access
Resource Type
journal article
Author(s)
Massachusetts Institute of Technology
Abstract
We present a new homonuclear recoupling sequence, CMAR, that allows observation of 2D 13C-13C correlation spectra at high magnetic fields and MAS frequencies (10-30 kHz). The main advantages of the sequence are that it provides efficient, broadband dipolar recoupling and concurrently decouples the 1H spins from the 13C's. Thus, no additional 1H decoupling is required during the mixing period, thereby significantly reducing the radio frequency power requirements for the experiment. Thus, CMAR significantly extends the range of applicability of the usual homonuclear recoupling techniques and should be of major interest for structure determinations of biomolecules at high magnetic fields. Copyright © 2006 American Chemical Society.
Start page
1776
End page
1777
Volume
128
Issue
6
Language
English
OCDE Knowledge area
Química orgánica
Scopus EID
2-s2.0-33244469975
PubMed ID
Source
Journal of the American Chemical Society
ISSN of the container
00027863
Sponsor(s)
National Institute of Biomedical Imaging and Bioengineering - R01EB001960 - NIBIB
Sources of information:
Directorio de Producción Científica
Scopus