Title
Synthesis and characterization of sacha inchi (Plukenetia volubilis L.) oil-based alkyd resin
Date Issued
01 November 2019
Access level
metadata only access
Resource Type
journal article
Publisher(s)
Elsevier B.V.
Abstract
Sacha Inchi (Plukenetia volubilis L.) is a wild oleaginous plant of the Euphorbiaceae family that grows in the Peruvian rainforest. The oil obtained from the seeds, which can reach 92% polyunsaturated fatty acid content, has been used as a raw material for the synthesis of alkyd resins. Short oil and medium oil alkyd resins in sacha inchi and linseed oil (control) were synthesized by a two-step alcoholysis-esterification process, reacting the oil with glycerol and phthalic and maleic anhydride in different proportions. The resins were structurally characterized using Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (1H NMR) spectroscopic techniques. The physicochemical properties of the resins in the liquid state, such as the acid value, colour, viscosity and density, were evaluated. The coating performance of the cured resins was studied by measuring the touch dry and hard dry times, hardness, chemical resistance, and thermal stability and by accelerated corrosion tests. We concluded that sacha inchi oil can be used as a raw material alternative to linseed oil in the synthesis of alkyd resins for industrial applications.
Volume
136
Language
English
OCDE Knowledge area
Química orgánica
Ciencia de los polímeros
Ingeniería de materiales
Subjects
Publication version
Version of Record
Scopus EID
2-s2.0-85071579536
Source
Progress in Organic Coatings
ISSN of the container
0300-9440
Sponsor(s)
This research was funded by the National Fund for Scientific and Technological Development and Technological Innovation (FONDECYT-Perú) and the PUCP agreement (Pontificia Universidad Católica del Perú / FONDECYT) [grant 166- 2015-FONDECYT-DE ]. The authors thank the Nuclear Magnetic Resonance Laboratory (Chemical Unit - PUCP) for the 1 H NMR analysis and the Materials Laboratory (Mechanical Engineering Unit - PUCP) for the thermogravimetric analysis.
Sources of information:
Directorio de Producción Científica
Scopus