Title
Analysis of architecture effect on hysteretic behavior of 3-D spin crossover nanostructures
Date Issued
01 November 2014
Access level
metadata only access
Resource Type
journal article
Author(s)
Chiruta D.
Jureschi C.
Graur A.
Dimian M.
Rotaru A.
Université de Versailles Saint-Quentin-en-Yvelines
Publisher(s)
Institute of Electrical and Electronics Engineers Inc.
Abstract
We have analyzed the hysteretic properties of thermal and pressure induced low spin (LS)虠high spin (HS) phase transition of a 3-D spin crossover (SCO) nanostructure when the cluster architecture is progressively changed from a cubic to a thin film. For solving the 3-D Ising-like Hamiltonian, the Monte Carlo metropolis technique is used, with the edge molecules trapped in HS state. The role of short- and long-range interactions on the SCO cooperativity has been investigated as well. The obtained results show that the cooperativity of a 3-D SCO system, characterized by the same number of molecules and the same interactions strength are strongly affected when going from a cubic 3-D to thin-film architecture. These results are discussed in terms of surface effects.
Volume
50
Issue
11
Language
English
OCDE Knowledge area
Ingeniería eléctrica, Ingeniería electrónica
Scopus EID
2-s2.0-84917694471
Source
IEEE Transactions on Magnetics
ISSN of the container
00189464
Sources of information: Directorio de Producción Científica Scopus