Title
Analytical solution of 1D Ising-like systems modified by weak long range interaction Application to spin crossover compounds
Date Issued
02 July 1999
Access level
metadata only access
Resource Type
journal article
Author(s)
Spiering H.
Varret F.
Université de Versailles
Publisher(s)
Springer New York
Abstract
It is well-known that 1D systems with only nearest neighbour interaction exhibit no phase transition. It is shown that the presence of a small long range interaction treated by the mean field approximation in addition to strong nearest neighbour interaction gives rise to hysteresis curves of large width. This situation is believed to exist in spin crossover systems where by the deformation of the spin changing molecules, an elastic coupling leads to a long range interaction, and strong bonding between the molecules in a chain compound leads to large values for nearest neighbour interaction constants. For this interaction scheme an analytical solution has been derived and the interplay between these two types of interaction is discussed on the basis of experimental data of the chain compound [Fe(Htrz)2(trz)](BF4)2 which exhibits a very large hysteresis of 50 K above RT at 370 K. The width and shape of the hysteresis loop depend on the balance between long and short range interaction. For short range interaction energies much larger than the transition temperature kBTt the hysteresis width is determined by the long range interaction alone.
Start page
271
End page
275
Volume
10
Issue
2
Language
English
OCDE Knowledge area
Física de la materia condensada Física y Astronomía
Scopus EID
2-s2.0-0001647135
Source
European Physical Journal B
ISSN of the container
14346028
Sources of information: Directorio de Producción Científica Scopus