Title
Enthalpy of formation of methyl benzoate: Calorimetry and consequences
Date Issued
01 January 2002
Access level
metadata only access
Resource Type
journal article
Author(s)
Roux M.
Temprado M.
Jiménez P.
Hosmane R.
Liebman J.
Consejo Superior de Investigaciones Científicas
Abstract
Methyl benzoate is a particularly simple and important organic compound. We are thus not prepared for the "discovery" that there are three relatively recent literature determinations of its enthalpy of formation that span a 15 kJ mol-1 range. The current study provides yet another, more reliable, measurement of the energy of combustion of this species, -3956.7 ± 3.1 kJ mol-1. Joined with one obtained from the literature a weighted average value for the enthalpy of formation in liquid phase for methyl benzoate can be given as ΔfHm°(l) = -332.8 ± 4.0 kJ mol-1 Combined with a literature suggested value for the enthalpy of vaporization we obtain the standard molar enthalpy of formation of methyl benzoate in gaseous state, ΔfHm°(g) = -276.1 ± 4.0 kJ mol-1. Confident of this new value, we reconcile a disconcerting disparity in the energetics of other methyl benzenecarboxylates discussed in the recent literature.
Start page
3611
End page
3613
Volume
4
Issue
15
Language
English
OCDE Knowledge area
Química
Scopus EID
2-s2.0-0036024870
Source
Physical Chemistry Chemical Physics
ISSN of the container
14639076
Sources of information: Directorio de Producción Científica Scopus