Title
Enthalpy of formation of methyl benzoate: Calorimetry and consequences
Date Issued
01 January 2002
Access level
metadata only access
Resource Type
journal article
Author(s)
Consejo Superior de Investigaciones Científicas
Abstract
Methyl benzoate is a particularly simple and important organic compound. We are thus not prepared for the "discovery" that there are three relatively recent literature determinations of its enthalpy of formation that span a 15 kJ mol-1 range. The current study provides yet another, more reliable, measurement of the energy of combustion of this species, -3956.7 ± 3.1 kJ mol-1. Joined with one obtained from the literature a weighted average value for the enthalpy of formation in liquid phase for methyl benzoate can be given as ΔfHm°(l) = -332.8 ± 4.0 kJ mol-1 Combined with a literature suggested value for the enthalpy of vaporization we obtain the standard molar enthalpy of formation of methyl benzoate in gaseous state, ΔfHm°(g) = -276.1 ± 4.0 kJ mol-1. Confident of this new value, we reconcile a disconcerting disparity in the energetics of other methyl benzenecarboxylates discussed in the recent literature.
Start page
3611
End page
3613
Volume
4
Issue
15
Language
English
OCDE Knowledge area
Química
DOI
Scopus EID
2-s2.0-0036024870
Source
Physical Chemistry Chemical Physics
ISSN of the container
14639076
Sources of information:
Directorio de Producción Científica
Scopus