cris.boxmetadata.label.title
Contribution of differential scattering of circularly polarized light to the optical rotatory dispersion of a sample
cris.boxmetadata.label.dateissued
01 browse.startsWith.months.november 1984
cris.boxmetadata.label.accesslevel
metadata only access
cris.boxmetadata.label.resourcetype
journal article
cris.boxmetadata.label.authors
cris.boxmetadata.label.publisher
Optica Publishing Group
cris.boxmetadata.label.abstract
A chiral scattering molecule has the ability to interact differently with circularly polarized light of opposite polarization. This phenomenon has been termed circular intensity differential scattering. It is shown that the differential-scattering phenomenon contributes to the total optical rotatory dispersion (ORD) of the sample. This contribution is independent of the presence of chromophores in the sample. From two general relations, (1) the Kronig–Kramers transforms, obeyed by linear, causal systems, and (2) the optical theorem, a result of energy conservation and power flow, the contribution of the preferential scattering of circularly polarized light to the ORD of the sample is formally obtained. It is seen that this contribution takes place through the circular preferential removal of the coherent part of the wave, i.e., the extinction (by means of scattering) of the transmitted radiation. It is shown that the use of approximations in the description of the internal field in the scattering equations can equivocally predict the absence of a scattering-dependent ORD contribution. © 1984 Optical Society of America.
cris.boxmetadata.label.citationstartpage
1114
cris.boxmetadata.label.citationendpage
1119
cris.boxmetadata.label.volume
1
cris.boxmetadata.label.issue
11
cris.boxmetadata.label.language
English
cris.boxmetadata.label.ocdeknowledgeArea
Medicina básica Física y Astronomía Nano-tecnología
cris.boxmetadata.label.doi
cris.boxmetadata.label.scopusidentifier
2-s2.0-0021523443
cris.boxmetadata.label.pubmedidentifier
cris.boxmetadata.label.source
Journal of the Optical Society of America A: Optics and Image Science, and Vision
cris.boxmetadata.label.containerissn
1084-7529
cris.boxmetadata.label.sponsor
National Institute of General Medical Sciences R37GM032543 NIGMS
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