Title
Stereoelectronic, strain, and medium effects on the protonation of cubylamine, a janus-like base
Date Issued
25 May 2003
Access level
open access
Resource Type
journal article
Author(s)
Abboud J.L.M.
Koppel I.A.
Alkorta I.
Della E.W.
Müller P.
Burk P.
Koppel I.
Pihl V.
Quintanilla E.
Consejo Superior de Investigaciones Científicas
Publisher(s)
Wiley-VCH Verlag
Abstract
The cubic structure of cubylamine (1NH2) is maintained on protonation in aqueous solution, but in the gas phase 1NH2 is irreversibly protonated on the carbon framework, leading to the formation of iminium ions through ring opening (see scheme).
Start page
2281
End page
2285
Volume
42
Issue
20
Language
English
OCDE Knowledge area
Química
Subjects
Scopus EID
2-s2.0-0037981610
Source
Angewandte Chemie - International Edition
ISSN of the container
14337851
Sources of information:
Directorio de Producción Científica
Scopus