Title
Solubility of triacylglycerols in supercritical carbon dioxide
Date Issued
01 November 2007
Access level
metadata only access
Resource Type
journal article
Author(s)
Soares B.
Paviani L.
Gonçalves L.
Cabral F.
State University of Campinas
Abstract
The solubility of refined corn and sunflower seed oils, babassu (Attalea funifera) and ucuuba (Virola sebifera) fats in supercritical carbon dioxide (SC-CO2) were measured in a temperature range from 40 to 80 °C and pressure between 200 and 350 bar. Under working conditions, the values of solubility showed retrograde behavior. Experimental SC-CO2 solubility data were collected from the literature for the following systems: tricaprylin (CCC), trilaurin (LLL), trimyristin (MMM), tripalmitin (PPP), tristearin (SSS), triolein (OOO), blackcurrant seed oil and canola seed oil, and analyzed together with the values obtained in this work. Chrastil's equation was used to correlate the solubility of oils in CO2 as a function of the temperature and density of the SC-CO2. An analysis of the results showed that the parameters of Chrastil's equation could be correlated to the fatty acid composition of the triacylglycerols. © 2007.
Start page
25
End page
31
Volume
43
Issue
1
Language
English
OCDE Knowledge area
Bioquímica, Biología molecular Química orgánica
Scopus EID
2-s2.0-34548525399
Source
Journal of Supercritical Fluids
ISSN of the container
08968446
Sponsor(s)
This work was supported by the São Paulo State Research Foundation (FAPESP 04/02181-3).
Sources of information: Directorio de Producción Científica Scopus