Title
Bi-functional interfaces by poly(ionic liquid) treatment in efficient pin and nip perovskite solar cells
Date Issued
01 August 2021
Access level
metadata only access
Resource Type
journal article
Author(s)
Caprioglio P.
Cruz D.S.
Caicedo-Dávila S.
Zu F.
Sutanto A.A.
Peña-Camargo F.
Kegelmann L.
Meggiolaro D.
Gregori L.
Wolff C.M.
Stiller B.
Perdigón-Toro L.
Köbler H.
Li B.
Gutierrez-Partida E.
Lauermann I.
Abate A.
Koch N.
De Angelis F.
Grancini G.
Abou-Ras D.
Nazeeruddin M.K.
Stolterfoht M.
Albrecht S.
Antonietti M.
Neher D.
Institute for Silicon Photovoltaics
Publisher(s)
Royal Society of Chemistry
Abstract
Approaches to boost the efficiency and stability of perovskite solar cells often address one singular problem in a specific device configuration. In this work, we utilize a poly(ionic liquid) (PIL) to introduce a multi-functional interlayer to improve the device efficiency and stability for different perovskite compositions and architectures. The presence of the PIL at the perovskite surface reduces the non-radiative losses down to 60 meV already in the neat material, indicating effective surface trap passivation, thereby pushing the external photoluminescence quantum yield up to 7%. In devices, the PIL treatment induces a bi-functionality of the surface where insulating areas act as a blocking layer reducing interfacial charge recombination and increasing the VOC, whereas, at the same time, the passivated neighbouring regions provide more efficient charge extraction, increasing the FF. As a result, these solar cells exhibit outstanding VOC and FF values of 1.17 V and 83% respectively, with the best devices reaching conversion efficiencies up to 21.4%. The PIL-treated devices additionally show enhanced stability during maximum power point tracking (>700 h) and unchanged efficiencies after 10 months of shelf storage. By applying the PIL to small and wide bandgap perovskites, and to nip cells, we corroborate the generality of this methodology to improve the efficiency in various cell architectures and perovskite compositions. This journal is
Start page
4508
End page
4522
Volume
14
Issue
8
Language
English
OCDE Knowledge area
Ingeniería de materiales
Scopus EID
2-s2.0-85113183483
Source
Energy and Environmental Science
ISSN of the container
17545692
Sponsor(s)
Funding text 1
S. A. acknowledges funding from the German Federal Ministry of Education and Research (BMBF), within the project ‘‘Material-forschung für die Energiewende’’ (grant no. 03SF0540), and the German Federal Ministry for Economic Affairs and Energy (BMWi) through the ‘‘PersiST’’ project (grant no. 0324037C). Additional funding came from HyPerCells (a Joint Graduate School of the Potsdam University and the HZB), the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Project-ID 182087777 – SFB 951, Project-ID 423749265 – SPP2196 (SURPRISE), Project-ID 424709669 – SPP2196 (HIPSTER) and the BMWi through the ‘‘P3T grant (grant no. 03EE1017C). G. G. acknowledges the ‘‘HY-NANO’’ project that has received funding from the European Research Council (ERC) Starting Grant 2018 under the European Union’s Horizon 2020 research and innovation programme (Grant agreement no. 802862). The authors are grateful for the financial support of the Helmholtz International Research School HI-SCORE (HIRS-0008).
Funding text 2
S. A. acknowledges funding from the German Federal Ministry of Education and Research (BMBF), within the project ‘‘Materialforschung fu¨r die Energiewende’’ (grant no. 03SF0540), and the German Federal Ministry for Economic Affairs and Energy (BMWi) through the ‘‘PersiST’’ project (grant no. 0324037C). Additional funding came from HyPerCells (a Joint Graduate School of the Potsdam University and the HZB), the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Project-ID 182087777 – SFB 951, Project-ID 423749265 – SPP2196 (SURPRISE), Project-ID 424709669 – SPP2196 (HIPSTER) and the BMWi through the ‘‘P3T grant (grant no. 03EE1017C). G. G. acknowledges the ‘‘HY-NANO’’ project that has received funding from the European Research Council (ERC) Starting Grant 2018 under the European Union’s Horizon 2020 research and innovation programme (Grant agreement no. 802862). The authors are grateful for the financial support of the Helmholtz International Research School HI-SCORE (HIRS-0008).
Horizon 2020 Framework Programme - 802862 -H2020
Sources of information:
Directorio de Producción Científica
Scopus