Title
Modeling of the electrical conductivity, thermal conductivity, and specific heat capacity of VO2
Date Issued
24 August 2018
Access level
metadata only access
Resource Type
journal article
Author(s)
Université de Poitiers
Publisher(s)
American Physical Society
Abstract
Based on Bruggeman's symmetric effective-medium formula and an explicit expression derived for the temperature evolution of the volume fractions of the metallic and isolating domains appearing during the heating and cooling of VO2, respectively, we develop a model to describe the hysteresis of its electrical and thermal conductivities as well as of its specific heat capacity. The model takes into account the average value and standard deviation of the transition temperatures of the individual domains, as well as their activation energies, which represent the driving force for the existence of the VO2 hysteresis. It is shown that the model's predictions driven by these three parameters related to the microstructure of VO2 are in good agreement with robust experimental data. Furthermore, as these parameters are intrinsically correlated to the doping, defect, strain, and interface effects of VO2, the proposed model enables the seamless integration of these effects, and therefore, its predictions are also expected to be useful for describing the thermal and electrical properties of composites based on VO2.
Volume
98
Issue
7
Language
English
OCDE Knowledge area
Física de partículas, Campos de la Física
Electroquímica
Scopus EID
2-s2.0-85052804749
Source
Physical Review B
ISSN of the container
24699950
Sponsor(s)
This work has been supported by the Cellule Énergie du CNRS through the Grant No. 267745.
Sources of information:
Directorio de Producción Científica
Scopus