Title
Crack formation and Zn diffusion in high-temperature processed poly-Si/ZnO:Al stacks
Date Issued
01 September 2014
Access level
metadata only access
Resource Type
journal article
Author(s)
Zachäus C.
Becker C.
Ruske F.
Institut Silizium-Photovoltaik
Publisher(s)
Elsevier
Abstract
In this paper, we investigated the feasibility of integrating aluminum doped zinc oxide (ZnO:Al) films as contacting layers into thin film polycrystalline silicon devices produced by solid phase crystallization at 600 °C for 20 h, rapid thermal annealing (RTA) at 1000 °C for 60 s and hydrogen passivation at 600 °C for 15 min. The RTA treatments were found to cause stress and crack formation in the poly-Si layer stack, which is due to thermal strain during high-temperature processing of the layer stacks. Furthermore, the diffusion of contaminants from the glass and especially from the ZnO:Al into the poly-Si is enhanced by RTA. The diffusion of Zn is accompanied by a degradation of the solar cell performance. Therefore, a SiN barrier was incorporated between the ZnO:Al layer and the poly-Si stack. The barrier is effectively preventing the diffusion of Zn impurities, which were measured by Secondary Ion Mass Spectrometry. Furthermore, optical microscopy images have shown that a decreasing thickness of the ZnO:Al layers results in lower stress and consequently in less crack formation in the layer stack, which can be explained by the interplay between layer tension and layer thickness in combination with different thermal expansion coefficients of the individual layers. In return, there is little diffusion of impurities for samples with a thin ZnO:Al layer, which significantly increases the electrical material quality of the poly-Si stack determined by the quasi-stationary open-circuit voltage method. © 2014 Elsevier B.V.
Start page
83
End page
87
Volume
566
Language
English
OCDE Knowledge area
Ingeniería de materiales Física de partículas, Campos de la Física
Scopus EID
2-s2.0-84906083765
Source
Thin Solid Films
ISSN of the container
00406090
Sponsor(s)
The authors thank M. Reiche from HZB for the help with deposition techniques (Sputter, PECVD) and the European Commission for the financial support by the FP7-Project PolySiMode (Contract No. 240826 ). This work was also supported by the state government of Berlin ( SENBWF ) in the framework of the program ‘Spitzenforschung und Innovation in den Neuen Ländern’ (Grant No. 03IS2151 ).
Sources of information: Directorio de Producción Científica Scopus