The Duffin-Kemmer-Petiau formalism with vector and scalar potentials is used to point out a few misconceptions diffused in the literature. It is explicitly shown that the scalar coupling makes the DKP formalism not equivalent to the Klein-Gordon formalism or to the Proca formalism, and that the spin-1 sector of the DKP theory looks formally like the spin-0 sector. With proper boundary conditions, scattering of massive bosons in an arbitrary mixed vector-scalar square step potential is explored in a simple way and effects due to the scalar coupling on the particle-antiparticle production and localization of bosons are analyzed in some detail. © Springer Science+Business Media, LLC 2009.