We have designed and experimentally put to test a protocol to synthesize and characterize pure, two-qubit states encoded in polarization and momentum (path) of light beams. Because these degrees of freedom are common to both classical and quantum light, it was possible to implement our protocol with classical light, thereby offering an advantageous and versatile testing ground. The experimental setup is robust and does not require state-dependent scheme modifications. We exhibited the capabilities of our protocol by generating three types of two-qubit states: Bell states, states with variable phases, and states with variable amplitudes.