Title
Density, stress, hardness and reduced Young's modulus of W-C:H coatings
Date Issued
20 December 2006
Access level
metadata only access
Resource Type
journal article
Author(s)
Janssen G.
Instituto Holandés para la Investigación de Metales
Publisher(s)
Elsevier
Abstract
Density, hardness and compressive stress of tungsten contained in an amorphous-hydrogenated-carbon matrix (W-C:H) have been studied as a function of composition and bias voltage. W-C:H coatings were deposited by reactive sputter deposition from a tungsten-carbide (WC) target on silicon substrate in an argon-acetylene plasma. W-C:H coatings obtained at different acetylene flow rates and substrate bias voltages, were characterized by scanning electron microscopy, X-ray diffraction, nanoindentation and substrate curvature method. It has been observed that compressive stress, hardness and reduced Young's modulus decrease when the acetylene flow is increased from 0 to 10 sccm. Also, compressive stress and hardness increases with the substrate bias voltage. In particular, for W-C:H coatings obtained at 5 sccm of acetylene flow, the compressive stress and hardness increase from - 1.6 GPa to - 3.2 GPa and from 19 GPa to 24 GPa, respectively, when increasing the substrate bias from 0 to 200 V. The variation of the internal stress, hardness and density of the coatings is discussed in terms of composition and structure of the W-C:H coatings. © 2006 Elsevier B.V. All rights reserved.
Start page
4284
End page
4288
Volume
201
Issue
7 SPEC. ISS.
Language
English
OCDE Knowledge area
Ingeniería de materiales
Subjects
Scopus EID
2-s2.0-33751222259
Source
Surface and Coatings Technology
ISSN of the container
02578972
Sponsor(s)
This research was carried out under project number MC7.02142B within the framework of the strategic Research program of The Netherlands Institute for Metals Research. X-ray diffraction was performed by N.M. van der Pers of the Department of Materials Science and Engineering (TUDelft). EPMA was performed by J. Kiersch of the Department of Materials Science and Engineering (TUDelft).
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